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Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphinmangan(III)-chlorid

95%

Synonym(e):

meso-Tetraphenylporphyrin-Mangan(III)-chlorid-Komplex

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About This Item

Empirische Formel (Hill-System):
C44H28ClMnN4
CAS-Nummer:
32195-55-4
Molekulargewicht:
703.11
Beilstein:
5699425
MDL-Nummer:
MFCD00012153
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24855405
NACRES:
NA.23

Assay

95%

Form

powder

Eignung der Reaktion

reagent type: catalyst
core: manganese

λmax

475 nm
583 nm (2nd)

SMILES String

Cl[Mn]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChIKey

MIUMWNDEIWVIEG-YKKPBKTHSA-M

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Verwandte Kategorien

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

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Sumana Kladsomboon et al.
Sensors (Basel, Switzerland), 18(10) (2018-09-23)
Hybrid optical gas sensors, based on different organic and inorganic materials, are proposed in this paper, with the aim of using them as optical artificial nose systems. Three types of organic and inorganic dyes, namely zinc-porphyrin, manganese-porphyrin, and zinc-phthalocyanine, were
Huang Xiao-wei et al.
Food chemistry, 197(Pt A), 930-936 (2015-12-01)
Trimethylamine (TMA) is a key measurement indicator for meat spoilage. In order to develop simple, cheap, and sensitive sensors for TMA detection, a nanoporous colorimetric sensor array (NCSA) was developed. A sol-gel method has been used to obtain TiO2 nanoporous
Majid Moghadam et al.
Bioorganic & medicinal chemistry letters, 16(7), 2026-2030 (2006-01-24)
Mild and efficient oxidation of Hantzsch 1,4-dihydropyridines with sodium periodate catalyzed by Mn(TTP)Cl supported on polystyrene-bound imidazole is reported. This heterogeneous catalyst is of great stability and reusability in the oxidation of 1,4-dihydropyridines with sodium periodate without significant loss of
B Cheng et al.
Acta crystallographica. Section C, Crystal structure communications, 52 ( Pt 2), 361-363 (1996-02-15)
The crystal structure of [Mn(TPP)Cl] in space group I4/m (where TPP is C44H28N4) has been determined. The unit cell contains two full molecules, with one eighth of a molecule unique. An out-of-plane model for the Mn atom was applied and
J Krzystek et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(6), 1113-1127 (2002-05-08)
High-field and -frequency electron paramagnetic resonance (HFEPR) spectroscopy has been used to study three complexes of high spin Manganese(III), 3d4, S = 2. The complexes studied were tetraphenylporphyrinatomanganese(III) chloride (MnTPPCI), phthalocyanatomanganese(III) chloride (MnPcCl), and (8,12-diethyl-2,3,7,13,17,18-hexamethylcorrolato)manganese(III) (MnCor). We demonstrate the ability
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