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(1-Bromethyl)benzol
97%
Synonym(e):
α-Methylbenzylbromid
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About This Item
Lineare Formel:
C6H5CH(CH3)Br
CAS-Nummer:
Molekulargewicht:
185.06
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
97%
Form
liquid
Brechungsindex
n20/D 1.56 (lit.)
bp
94 °C/16 mmHg (lit.)
Dichte
1.356 g/mL at 25 °C (lit.)
Funktionelle Gruppe
bromo
phenyl
SMILES String
CC(Br)c1ccccc1
InChI
1S/C8H9Br/c1-7(9)8-5-3-2-4-6-8/h2-7H,1H3
InChIKey
CRRUGYDDEMGVDY-UHFFFAOYSA-N
Anwendung
(1-Bromoethyl)benzene has been employed:
- in controlled radical polymerization of styrene
- in asymmetric esterification of benzoic acid in the presence of a chiral cyclic guanidine
- as initiator in the synthesis of bromine terminated polyp-methoxystyrene and polystyrene via atom transfer radical polymerization
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
179.6 °F - closed cup
Flammpunkt (°C)
82 °C - closed cup
Persönliche Schutzausrüstung
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Macromolecular Rapid Communications, 20, 351-355 (1999)
Synthesis of block copolymers by combination of atom transfer radical and promoted cationic polymerization mechanisms.
Baskan Duz A and Yagci Y.
Eur. Polymer J., 35(11), 2031-2038 (1999)
Simple preparation of chiral 1, 3-dimethyl-2-iminoimidazolidines (monocyclic guanidines) and applications to asymmetric alkylative esterification.
Isobe T, et al.
Tetrahedron Asymmetry, 9(10), 1729-1735 (1998)
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A hypervalent (HV) iodine(III)-containing crosslinker, (diacryloyloxyiodo)benzene, is synthesized and its crystal structure is reported. Highly branched polymers with hypervalent iodine(III) groups as the building blocks present at the branching points are synthesized by copolymerization of tert-butyl acrylate and the diacrylate
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Diblock copolymers composed of a polystyrene first block and a PEG-fluoroalkyl chain-modified polystyrene second block were synthesized by controlled atom transfer radical polymerization (ATRP), starting from the same polystyrene macroinitiator. The wettability of the polymer film surfaces was investigated by
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