234192

1-Hexanthiol

95%

• Synonym(e): Hexylmercaptan, Mercaptan C₆
• Lineare Formel: CH₃(CH₂)₅SH
• CAS-Nummer: 111-31-9
• Molekulargewicht: 118.24
• Beilstein: 1731295
• EG-Nummer: 203-857-0
• MDL-Nummer: MFCD00004909
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24854028
• NACRES: NA.23

Eigenschaften

• Assay: 95%
• Form: liquid
• Brechungsindex: n20/D 1.450
• bp: 150-154 °C (lit.)
• mp (Schmelzpunkt): −81-−80 °C (lit.)
• Dichte: 0.832 g/mL at 25 °C
• SMILES String: CCCCCCS
• InChI: 1S/C6H14S/c1-2-3-4-5-6-7/h7H,2-6H2,1H3
• InChIKey: PMBXCGGQNSVESQ-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

1-Hexanethiol is an organothiol that forms a self-assembled monolayer (SAM) on a variety of nanoparticles. It consists of S head group, CH₂ alkane chain, and CH₃ terminal group.

Anwendung

1-Hexanethiol can be mixed with 4-mercaptophenol to functionalize gold nanoparticles (AuNPs) for use as chemi-resistive sensors. It can also form a protective coating against oxidative reactions and contaminating layers on copper surfaces. It can also be used as a thiol based ligand which finds potential application as a semiconducting material in thin film solar cells.
It is used to tune the electrical characteristics in networked carbon nanotube field-effect transistors. It is also used as a monolayer on copper surfaces to retard surface oxidation during exposure to the environment which can then be desorbed effectively with an annealing step in inert N₂ to provide a clean Cu surface.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H302
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P301 + P312
• Gefahreneinstufungen: Acute Tox. 4 Oral - Flam. Liq. 3
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 86.0 °F - closed cup
• Flammpunkt (°C): 30 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter