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1-Methylhomopiperazin
97%
Synonym(e):
Hexahydro-1-methyl-1H-1,4-diazepin
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About This Item
Empirische Formel (Hill-System):
C6H14N2
CAS-Nummer:
Molekulargewicht:
114.19
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
97%
Form
liquid
Brechungsindex
n20/D 1.477 (lit.)
bp
74-75 °C/35 mmHg (lit.)
Dichte
0.918 g/mL at 25 °C (lit.)
Lagertemp.
−20°C
SMILES String
CN1CCCNCC1
InChI
1S/C6H14N2/c1-8-5-2-3-7-4-6-8/h7H,2-6H2,1H3
InChIKey
FXHRAKUEZPSMLJ-UHFFFAOYSA-N
Verwandte Kategorien
Allgemeine Beschreibung
1-Methylhomopiperazine undergoes coupling reaction with a series of diazonium salts to afford the 4-methyl-1-[2-aryl-1-diazenyl]-1,4-diazepanes.
Anwendung
1-Methylhomopiperazine was used in the synthesis of:
- novel benzimidazole derivatives having pharmacological activities
- platinum(II) substituted disulfide complexes
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
Lagerklassenschlüssel
3 - Flammable liquids
WGK
WGK 3
Flammpunkt (°F)
113.0 °F - closed cup
Flammpunkt (°C)
45 °C - closed cup
Persönliche Schutzausrüstung
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Homopiperazine platinum (II) complexes containing substituted disulfide groups: crystal structure of [Pt II(homopiperazine)(diphenylsulfide) Cl] NO3.
Ali MS, et al.
Polyhedron, 21(1), 125-131 (2002)
H Nakano et al.
Bioorganic & medicinal chemistry, 8(2), 373-380 (2000-03-18)
Novel benzimidazole derivatives were synthesized and their pharmacological activities were examined. These compounds showed a good suppressive action on histamine release from rat peritoneal mast cells produced by antigen-antibody reaction, an antagonistic action on guinea pig ileum contraction caused by
Synthesis and characterization of a series of 4-methyl-1-[2-aryl-1-diazenyl]-1, 4-diazepanes and 1, 4-di-[2-aryl-1-diazenyl]-1, 4-diazepanes.
Moser SL and Vaughan K.
Canadian Journal of Chemistry, 82(!2), 1725-1735 (2004)
Son T Nguyen et al.
Bioorganic & medicinal chemistry, 23(9), 2024-2034 (2015-03-31)
Recently we described a novel pyranopyridine inhibitor (MBX2319) of RND-type efflux pumps of the Enterobacteriaceae. MBX2319 (3,3-dimethyl-5-cyano-8-morpholino-6-(phenethylthio)-3,4-dihydro-1H-pyrano[3,4-c]pyridine) is structurally distinct from other known Gram-negative efflux pump inhibitors (EPIs), such as 1-(1-naphthylmethyl)-piperazine (NMP), phenylalanylarginine-β-naphthylamide (PAβN), D13-9001, and the pyridopyrimidine derivatives. Here
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