183695

2′-Bromacetophenon

99%

• Synonym(e): 1-Acetyl-2-brom-benzol
• Lineare Formel: BrC₆H₄COCH₃
• CAS-Nummer: 2142-69-0
• Molekulargewicht: 199.04
• Beilstein: 1931534
• EG-Nummer: 218-398-1
• MDL-Nummer: MFCD00000067
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24851070
• NACRES: NA.22

Eigenschaften

• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.568 (lit.)
• Dichte: 1.476 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: bromo; ketone
• SMILES String: CC(=O)c1ccccc1Br
• InChI: 1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
• InChIKey: PIMNFNXBTGPCIL-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

Anwendung

2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 230.0 °F - closed cup
• Flammpunkt (°C): 110 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter