145262

(Ethoxycarbonylmethyl)dimethylsulfoniumbromid

97%

• Lineare Formel: C₂H₅O₂CCH₂S(CH₃)₂Br
• CAS-Nummer: 5187-82-6
• Molekulargewicht: 231.15
• EG-Nummer: 225-968-3
• MDL-Nummer: MFCD00830557
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24848710
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• mp (Schmelzpunkt): 90-94 °C (lit.)
• SMILES String: Br.CCOC(=O)C[S](C)C
• InChI: 1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1
• InChIKey: JXFPTJYKYKVENJ-UHFFFAOYSA-M

Beschreibung

Anwendung

(Ethoxycarbonylmethyl)dimethylsulfonium bromide was used in synthesis of α-sulfanyl-β-amino acid derivatives by using nanocrystalline magnesium oxide. It was used during cyclopropanation of (-)-(S)-2-(p-tolylsulfinyl)cyclopent-2-enone.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves