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Merck

10035

Sigma-Aldrich

Ammoniummetawolframat Hydrat

≥85% WO3 basis (gravimetric)

Synonym(e):

AMT, Hexaammonium wolframate hydrate, Tungstic acid hexaammonium salt

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About This Item

Lineare Formel:
(NH4)6H2W12O40 · xH2O
CAS-Nummer:
Molekulargewicht:
2956.30 (anhydrous basis)
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.23

Assay

≥85% WO3 basis (gravimetric)

Form

solid

Eignung der Reaktion

reagent type: catalyst
core: tungsten

Verunreinigungen

≤0.005% water-insoluble matter

Verlust

≤15% loss on ignition

mp (Schmelzpunkt)

100 °C (dec.) (lit.)

SMILES String

N.N.N.N.N.N.O.O[W]1O[W](O)(=O)(O1)O[W]2(=O)(=O)O[W](O)(=O)(O2)O[W]3(=O)(=O)O[W](O)(=O)(O3)O[W]4(=O)(=O)O[W](O)(=O)(O[W]5(=O)(=O)O[W](O)(=O)(O[W]6(=O)(=O)O[W](O)(O)O6)O5)O4

InChI

1S/6H3N.9H2O.32O.12W/h6*1H3;9*1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*+1;+2/p-8

InChIKey

ZBHPUDGBNLMJQH-UHFFFAOYSA-F

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Allgemeine Beschreibung

Ammonium metatungstate hydrate is used as a starting material to prepare catalysts for the reduction of NOx. It can also be used as a precursor to synthesize tungsten oxide thin films by chemical vapor deposition method.

Anwendung

  • Effect of morphology properties of NiW catalysts on hydrodesulfurization for individual sulfur compounds in fluid catalytic cracking diesel: This research discusses the influence of ammonium metatungstate hydrate in the preparation of NiW catalysts, focusing on its role in hydrodesulfurization processes (X Tao et al., 2014).
  • Preparation of quaternary tungsten bronze nanoparticles by a thermal decomposition of ammonium metatungstate with oleylamine: This study examines the decomposition pathways of ammonium metatungstate hydrate into metatungstate anions and their applications in creating tungsten bronze nanoparticles (J Choi et al., 2015).

Piktogramme

CorrosionExclamation mark

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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Daniel Delgado et al.
Dalton transactions (Cambridge, England : 2003), 49(38), 13282-13293 (2020-09-17)
Materials from the WO3-Nb2O5 system, presenting bronze-type crystal structures, display outstanding functional properties for several applications as thermoelectric materials, lithium-ion battery electrodes, or catalysts. In this work, a series of W-Nb-O oxide bronzes have been synthesized by the hydrothermal method
Ze-Da Meng et al.
Nanoscale research letters, 6(1), 459-459 (2011-07-22)
WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution
Alessandro Chieregato et al.
ChemSusChem, 8(2), 398-406 (2014-12-10)
Glycerol surplus from biodiesel synthesis still represents a major problem in the biofuel production chain. Meanwhile, those in the acrylic acid market are looking for new processes that are able to offer viable alternatives to propylene-based production. Therefore, acrylic acid
Thandavarayan Maiyalagan et al.
Analytical chemistry, 86(15), 7849-7857 (2014-07-16)
Supported tungsten carbide is an efficient and vital nanomaterial for the development of high-performance, sensitive, and selective electrochemical sensors. In this work, tungsten carbide with tube-like nanostructures (WC NTs) supported platinum nanoparticles (PtNPs) are synthesized and explored as an efficient
Luqman Atanda et al.
ChemSusChem, 8(17), 2907-2916 (2015-08-05)
A water-THF biphasic system containing N-methyl-2-pyrrolidone (NMP) was found to enable the efficient synthesis of 5-hydroxymethylfurfural (HMF) from a variety of sugars (simple to complex) using phosphated TiO2 as a catalyst. Fructose and glucose were selectively converted to HMF resulting

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