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72253

Sigma-Aldrich

Nickel(II) nitrate hexahydrate

purum p.a., crystallized, ≥97.0% (KT)

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About This Item

Linear Formula:
Ni(NO3)2 · 6H2O
CAS Number:
13478-00-7
Molecular Weight:
290.79
EC Number:
236-068-5
MDL number:
MFCD00149805
UNSPSC Code:
12352300
PubChem Substance ID:
329763936
NACRES:
NA.21

grade

purum p.a.

Quality Level

200

Assay

≥97.0% (KT)

form

crystals

quality

crystallized

mp

56 °C (lit.)

density

2.05 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤500 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;

InChI key

AOPCKOPZYFFEDA-UHFFFAOYSA-N

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General description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.

Application

Nickel(II) nitrate hexahydrate may be used as precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders and Ni (II) oxide aerogels.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2?6H2O, in comparison to Co(NO3)2?6H2O and Ca(NO3)2?4H2O.
Brockner W, et al.
Thermochimica Acta, 456(1), 64-68 (2007)
Monolithic nickel (II)-based aerogels using an organic epoxide: the importance of the counterion.
Gash AE, et al.
Journal of Non-Crystalline Solids, 350, 145-151 (2004)
Synthesis and structural characterization of layered Li[Ni1/3Co1/3Mn1/3]O2 cathode materials by ultrasonic spray pyrolysis method.
Park SH, et al.
Electrochimica Acta, 49(4), 557-563 (2004)
Robert Jirásko et al.
Journal of mass spectrometry : JMS, 43(9), 1274-1284 (2008-03-14)
This work demonstrates the application of electrospray ionization mass spectrometry (ESI-MS) using two different mass analyzers, ion trap and hybrid quadrupole time-of-flight (QqTOF) mass analyzer, for the structural characterization of Ni(II) complexes of Schiff bases of (S)-N-(2-benzoylphenyl)-1-benzylpyrrolidine-2-carboxamide with different amino
Nickel nitrate and K-ferrocyanide in fixative for electron microscopy as tracer of extracellular space.
L S Gutiérrez et al.
Microscopia electronica y biologia celular : organo oficial de las Sociedades Latinoamericana de Microscopia Electronica e Iberoamericana de Biologia Celular, 12(2), 217-229 (1988-12-01)
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