750190

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

95%

• Synonym(s): Pd-117
• Empirical Formula (Hill Notation): C₃₆H₂₈Cl₂OP₂Pd
• CAS Number: 205319-06-8
• Molecular Weight: 715.88
• MDL number: MFCD09953446
• UNSPSC Code: 12352300
• PubChem Substance ID: 329766057
• NACRES: NA.22

Properties

• Assay: 95%
• form: powder
• mp: 243-250 °C
• storage temp.: 2-8°C
• SMILES string: Cl[Pd]Cl.O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
• InChI: 1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;;;/h1-28H;2*1H;/q;;;+2/p-2
• InChI key: VYOUBMJFTDMKRR-UHFFFAOYSA-L

Description

General description

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is a palladium(II) complex containing two chloride ligands and two (2-(diphenylphosphino)phenyl)ether ligands coordinated to the palladium center. It is used as a catalyst for the cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z, E dienes.

Application

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is used as an efficient catalyst in the coupling reaction.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable