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727695

Sigma-Aldrich

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥98.5% (HPLC)

Synonym(s):

AMIMTFSI

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About This Item

Empirical Formula (Hill Notation):
C9H11F6N3O4S2
CAS Number:
Molecular Weight:
403.32
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥98.5% (HPLC)

form

liquid

impurities

≤1% water

SMILES string

C[n+]1ccn(CC=C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C7H11N2.C2F6NO4S2/c1-3-4-9-6-5-8(2)7-9;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3,5-7H,1,4H2,2H3;/q+1;-1

InChI key

DHMWATGUEVQTIY-UHFFFAOYSA-N

General description

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide is an ionic liquid that can be prepared by reacting 1-allyl-3-methylimidazolium chloride and lithium bis(trifluoromethylsulfonyl)imide under microwave conditions.

Application

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide can be used to prepare AMIMTFSI-propylene carbonate based electrolyte, with potential application in lithium-ion batteries. It also finds application in alkanes/alkenes separation process. AMIMTFSI can be used as a surface protector to develop luminescent silicon nanoparticles.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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(Liquid+ liquid) equilibrium for the ternary systems {heptane+ toluene+ 1-allyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide} and {heptane+ toluene+ 1-methyl-3-propylimidazolium bis (trifluoromethylsulfonyl) imide} ionic liquids
Garcia, Silvia, et al.
The Journal of Chemical Thermodynamics, 43.11, 1641-1645 (2011)
Thermodynamics and selectivity of separation based on activity coefficients at infinite dilution of various solutes in 1-allyl-3-methylimidazolium bis {(trifluoromethyl) sulfonyl} imide ionic liquid.
Wlazlo M, et al.
The Journal of Chemical Thermodynamics, 102, 39-47 (2016)
Hassan M Albishri et al.
Talanta, 200, 107-114 (2019-05-01)
Acetylcholine (ACh) and its precursor choline (Ch) play important roles in many biological processes. It is expected that Alzheimer's disease is occurred due to the reduction in synthesis of ACh. On the other hand, the increase in the level of
Mixtures of unsaturated imidazolium based ionic liquid and organic carbonate as electrolyte for Li-ion batteries.
Wang M, et al.
Electrochimica Acta, 95, 301-307 (2013)
Luminescent silicon nanoparticles covered with ionic liquid.
Miyano M, et al.
Materials Letters, 141, 359-361 (2015)

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