696668

Nickel(II) chloride ethylene glycol dimethyl ether complex

98%

• Synonym(s): Dichloro(dimethoxyethane)nickel, NiCl₂ glyme
• Linear Formula: NiCl₂:CH₃OCH₂CH₂OCH₃
• CAS Number: 29046-78-4
• Molecular Weight: 219.72
• MDL number: MFCD00013481
• UNSPSC Code: 12161600
• PubChem Substance ID: 329761848
• NACRES: NA.22

Properties

• Assay: 98%
• form: powder
• reaction suitability: core: nickel; reagent type: catalyst
• mp: >300 °C
• SMILES string: Cl[Ni]Cl.COCCOC
• InChI: 1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
• InChI key: OCMNCWNTDDVHFK-UHFFFAOYSA-L

Description

Application

Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:

• As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
• As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF₃ compounds.
• For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO₂ to CO.
• As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H261,H301,H315,H319,H334,H350,H400
• Precautionary Statements: P202 - P231 + P232 - P273 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react 2
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves