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658383

Sigma-Aldrich

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Synonym(s):

[(ppy)2IrCl]2

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About This Item

Empirical Formula (Hill Notation):
C44H32Cl2Ir2N4
CAS Number:
92220-65-0
Molecular Weight:
1072.09
MDL number:
MFCD07784515
UNSPSC Code:
12352103
PubChem Substance ID:
24884350
NACRES:
NA.23

form

solid

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

465 nm

SMILES string

Cl[Ir](c1ccccc1-c2ccccn2)c3ccccc3-c4ccccn4.Cl[Ir](c5ccccc5-c6ccccn6)c7ccccc7-c8ccccn8

InChI

1S/4C11H9N.2ClH.2Ir/c4*1-2-6-10(7-3-1)11-8-4-5-9-12-11;;;;/h4*1-9H;2*1H;;/q;;;;;;2*+1/p-2

InChI key

NARZJSRZFGZBIZ-UHFFFAOYSA-L

Application

Precursor for several OLED Iridium compounds. Has some use as a catalyst and in OLEDs.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of the American Chemical Society, 106, 6647-6647 (1984)

Articles

Materials Design Concepts for Efficient Blue OLEDs: A Joint Theoretical and Experimental Study

Since their discovery, organic light emitting devices (OLEDs) have evolved from a scientific curiosity into a technology with applications in flat panel displays and the potential to revolutionize the lighting market. During their relatively short history, the technology has rapidly advanced, and device efficiencies have increased more than 20-fold, approaching the theoretical limit for internal quantum efficiencies.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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