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52865

Sigma-Aldrich

Sodium 1-hexanesulfonate monohydrate

≥98.0% (T)

Synonym(s):

1-Hexanesulfonic acid sodium salt monohydrate

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About This Item

Linear Formula:
CH3(CH2)4CH2SO3Na · H2O
CAS Number:
207300-91-2
Molecular Weight:
206.24
Beilstein:
3727014
EC Number:
220-601-3
MDL number:
MFCD00149549
UNSPSC Code:
12352100
PubChem Substance ID:
57651386
NACRES:
NA.22

Assay

≥98.0% (T)

form

solid

SMILES string

O.[Na+].CCCCCCS([O-])(=O)=O

InChI

1S/C6H14O3S.Na.H2O/c1-2-3-4-5-6-10(7,8)9;;/h2-6H2,1H3,(H,7,8,9);;1H2/q;+1;/p-1

InChI key

CLCGFJYKZGFGSQ-UHFFFAOYSA-M

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Application

Sodium 1-hexanesulfonate monohydrate can be used as a catalyst to synthesize:     
  • Amidoalkyl naphthols by three-component reaction of β-naphthol, aldehydes, and urea.      
  • Aminophosphonates by the reaction of aldehydes/ketones with amines.

It can also be used as a reactant to prepare polynuclear oxidobismuth sulfonates by reacting with sodium 2-methyl-2-propensulfonate and tetra-μ3-hydroxyhexakis(nitrato-κO)tetra-μ3-oxohexabismuth in DMSO.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Kirti S Niralwad et al.
Ultrasonics sonochemistry, 17(5), 760-763 (2010-03-17)
1-Hexanesulphonic acid sodium salt was found to be an efficient catalyst for the green synthesis of alpha-aminophosphonates by the coupling of aldehydes/ketone, an amine and triethyl phosphite under ultrasound irradiation at ambient temperature for appropriate time to furnish the desired
Philip Zakaria et al.
Electrophoresis, 23(17), 2821-2832 (2002-09-11)
The separation of a series of aromatic carboxylic acids, sulfonates and opiates using electrokinetic chromatography employing a mixture of the soluble cationic polymer poly(diallydimethylammonium chloride) (PDDAC) and the amphiphilic anion hexanesulfonate as pseudostationary phases is described. In this system, the
A R Calhoun et al.
Journal of colloid and interface science, 309(2), 505-510 (2007-03-03)
Measurements have been made to determine the solubility of ethane, C2H6, in aqueous solutions of four different surfactants of the linear alkanesulfonate class at 25 degrees C. The surfactants, sodium 1-pentanesulfonate, sodium 1-hexanesulfonate, sodium 1-heptanesulfonate, and sodium 1-octanesulfonate, all share
Ana L Costa et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(34), 12069-12078 (2015-07-29)
Zn-Al layered double hydroxides (LDHs) containing solely indigo carmine (IC) or 1-hexanesulfonate (HS) anions, or a mixture of the two with different HS/IC molar ratios, were prepared by the direct synthesis method and characterized by various techniques. Hydrotalcite-type phases were
N M Kovalchuk et al.
Journal of colloid and interface science, 459, 250-256 (2015-08-25)
Mixed solutions of cationic and anionic surfactants show considerable synergism in their wetting behaviour, but their spreading is affected considerably by the phase separation processes. The valuable information about wetting properties of synergetic mixtures can be obtained by using mixtures

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