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484385

Sigma-Aldrich

Gold(III) chloride solution

99.99% trace metals basis, 30 wt. % in dilute HCl

Synonym(s):

Auric chloride, Gold trichloride

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About This Item

Linear Formula:
HAuCl4
CAS Number:
16903-35-8
Molecular Weight:
339.79
MDL number:
MFCD00011322
UNSPSC Code:
12352302
PubChem Substance ID:
24871946
NACRES:
NA.23

Quality Level

200

Assay

99.99% trace metals basis

form

liquid

composition

Au, 17 wt. %

concentration

30 wt. % in dilute HCl

impurities

≤150.0 ppm Trace Metal Analysis

density

1.637 g/mL at 25 °C

SMILES string

[H][Au](Cl)(Cl)(Cl)Cl

InChI

1S/Au.4ClH/h;4*1H/q+3;;;;/p-3

InChI key

VDLSFRRYNGEBEJ-UHFFFAOYSA-K

General description

Gold(III) chloride solution, commonly called asauric chloride or auric acid is widely used as a precursor to synthesize goldcomplexes and stable gold nanoparticles. It also finds application in the fieldof catalysis.

Application

Noble-Metal Nanostructures with Controlled Morphologies
Gold(III) chloride solution can be used:
  • As a starting material to prepare thiolate-stabilized gold nanoparticles.
  • As an efficient catalyst for single-pot oxidative functionalization of alkanes and alcohols.
  • As a catalyst for diastereoselective alkylation reactions with chiral benzylic acetates.
Suitable precursormaterial for the synthesis of Gold nanorods by using Seed-Mediated Growth Methodwhich has been used for cancer cell imaging and photothermal therapy.

Signal Word

Danger

Hazard Statements

H290,H302,H314,H373,H411

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

Target Organs

Kidney

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR0202
MKCQ4504
MKCQ0103
MKCP2669
MKCN9327

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Electronics and Self-Assembly with Single Molecules.
Moth-Poulsen K, et al.
Material Matters, 4(3), 80-80 (2009)
Nanoparticle Targeting at Cells.
de la Fuente JM, et al.
Langmuir, 22, 3286-3293 (2006)
Fink, J. et al.
Chemistry of Materials, 10, 922-922 (1998)
Xianqing Tian et al.
Talanta, 93, 79-85 (2012-04-10)
Graphene decorated with gold nanoparticles (AuNPs-β-CD-Gra) has been synthesized by in situ thermal reduction of graphene oxide and HAuCl(4) with β-cyclodextrin (β-CD) under alkaline condition. The AuNPs-β-CD-Gra product was well characterized by infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy
Ja-an Annie Ho et al.
Analytical chemistry, 84(7), 3246-3253 (2012-03-01)
In this paper, we describe a simple one-pot method, employing l-3,4-dihydroxyphenylalanine (L-DOPA) as a reducing/capping reagent, for the synthesis of fluorescent gold nanoclusters (AuNCs). Within a short reaction time of 15 min (excluding the time required for purification), this strategy
View All Related Papers

Articles

Electronics and Self-Assembly with Single Molecules

Single molecule electronics is the endeavour of constructing electronic circuitry with single molecules as the fundamental building block.

Noble-Metal Nanostructures with Controlled Morphologies

Noble-metal nanostructures are widely used in a variety of applications ranging from catalysis to electronics, surface plasmon resonance (SPR), surface-enhanced Raman scattering (SERS), and biomedical research.

Gold Nanorod Synthesis

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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