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Key Documents

244406

Sigma-Aldrich

1-Dodecyne

98%

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About This Item

Linear Formula:
CH3(CH2)9C≡CH
CAS Number:
Molecular Weight:
166.30
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

liquid

refractive index

n20/D 1.434 (lit.)

bp

215 °C (lit.)

mp

−19 °C (lit.)

density

0.778 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCC#C

InChI

1S/C12H22/c1-3-5-7-9-11-12-10-8-6-4-2/h1H,4-12H2,2H3

InChI key

ZVDBUOGYYYNMQI-UHFFFAOYSA-N

Application

1-Dodecyne was used in the synthesis of stable ruthenium nanoparticles.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 4 - Eye Dam. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

174.2 °F - closed cup

Flash Point(C)

79 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Xiongwu Kang et al.
Journal of the American Chemical Society, 134(3), 1412-1415 (2012-01-11)
Stable ruthenium nanoparticles were prepared by the self-assembly of 1-dodecyne onto the "bare" Ru colloid surface. The formation of a Ru-vinylidene (Ru═C═CH-R) interfacial bonding linkage was confirmed by the specific reactivity of the nanoparticles with imine derivatives to form a
Davide Albani et al.
Nature communications, 9(1), 2634-2634 (2018-07-08)
Ensemble control has been intensively pursued for decades to identify sustainable alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of alkynes in industrial organic synthesis. Although the geometric and electronic requirements are known, a literature survey illustrates

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