223662

Tris(triphenylphosphine)ruthenium(II) dichloride

97%

• Sinonimo/i: Tris(triphenylphosphine)dichlororuthenium, Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
• Formula condensata: [(C₆H₅)₃P]₃RuCl₂
• Numero CAS: 15529-49-4
• Peso molecolare: 958.83
• Beilstein: 4935939
• Numero CE: 239-569-7
• Numero MDL: MFCD00013077
• Codice UNSPSC: 12161600
• ID PubChem: 24853394
• NACRES: NA.22

Proprietà

• Saggio: 97%
• Impiego in reazioni chimiche: core: ruthenium; reagent type: catalyst; reaction type: C-H Activation
• Stringa SMILE: Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
• InChI: 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2; WIWBLJMBLGWSIN-UHFFFAOYSA-L

Descrizione

Applicazioni

Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl₂(PPh₃)₃] can be used as a catalyst to synthesize:

• Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp³ C-H bond activation of primary alcohols in the presence of Lewis acid.
• Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
• 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
• Vinyl chloride monomer by hydrochlorination reaction of acetylene.

RuCl₂(PPh₃)₃ can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: dust mask type N95 (US), Eyeshields, Gloves