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72301

Sigma-Aldrich

9-(2-Carboxy-2-cyanovinyl)julolidine

BioReagent, suitable for fluorescence, ≥97.0% (HPLC)

Synonyme(s) :

9-([E]-2-Carboxy-2-cyanovinyl)julolidine, CCVJ

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About This Item

Formule empirique (notation de Hill):
C16H16N2O2
Numéro CAS:
142978-18-5
Poids moléculaire :
268.31
Numéro MDL:
MFCD00274408
Code UNSPSC :
12352108
ID de substance PubChem :
57652410
Nomenclature NACRES :
NA.32

Gamme de produits

BioReagent

Pureté

≥97.0% (HPLC)

Forme

solid

Solubilité

DMSO: soluble
chloroform: soluble

Fluorescence

λex 433 nm; λem 500 nm in 50 mM Tris pH 8.0; 40% glycerol

Adéquation

suitable for fluorescence

Chaîne SMILES 

OC(=O)\C(=C\c1cc2CCCN3CCCc(c1)c23)C#N

InChI

1S/C16H16N2O2/c17-10-14(16(19)20)9-11-7-12-3-1-5-18-6-2-4-13(8-11)15(12)18/h7-9H,1-6H2,(H,19,20)/b14-9+

Clé InChI

JXENNHTVELFRHV-NTEUORMPSA-N

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Application

Fluorescent probe for binding to proteins etc., quantum yield increases by decreasing free rotation: fluorescent molecular rotor.

Conditionnement

Bottomless glass bottle. Contents are inside inserted fused cone.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Elisabeth Ablinger et al.
International journal of pharmaceutics, 441(1-2), 255-260 (2012-12-04)
A differential scanning fluorimetry (DSF) based high-throughput screening assay with the fluorescent molecular rotor CCVJ (9-(2-carboxy-2-cyanovinyl)julolidine) was developed. CCVJ is mainly sensitive to viscosity and less to polarity in comparison to polarity-sensitive dyes like SYPRO Orange, which was commonly used
Christopher Rumble et al.
The journal of physical chemistry. A, 116(44), 10786-10792 (2012-10-27)
The photochemistry of the rotor probe 9-(2-carboxy-2-cyanovinyl)julolidine (CCVJ) was studied to elucidate a curious effect of fluid flow previously reported. The apparent sensitivity to fluid motion observed in CCVJ but not in the closely related molecule 9-(dicyanovinyl)julolidine (DCVJ) is found
Xingyun Peng et al.
Carbohydrate polymers, 250, 116859-116859 (2020-10-15)
Fluorescence emissions of molecular rotors (MRs) are affected by local restrictions to molecular motion, and therefore it was considered that MRs can be used as structural probes of biopolymers. In this study, 9-(2-carboxy-2-cyanovinyl)-julolidine (CCVJ), a hydrophilic MR, was used to
James A Levitt et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 12(3), 662-672 (2011-02-18)
We present polarization-resolved fluorescence measurements of fluorescent molecular rotors 9-(2-carboxy-2-cyanovinyl)julolidine (CCVJ), 9-(2,2-dicyanovinyl)julolidine (DCVJ), and a meso-substituted boron dipyrromethene (BODIPY-C(12)). The photophysical properties of these molecules are highly dependent on the viscosity of the surrounding solvent. The relationship between their quantum
Sagar Satpathi et al.
Organic & biomolecular chemistry, 17(21), 5392-5399 (2019-05-21)
Here, we have explored the light-up property of coumarin 343 (C343) selectively towards various i-motif DNAs based on the recognition of hemi-protonated cytosine-cytosine base pairing, unlike other DNA structures. We have also demonstrated the versatile ability of this i-motif ligand

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