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685070

Sigma-Aldrich

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene]

99.9%

Synonyme(s) :

F8T2, Poly(9,9-dioctylfluorene-alt-bithiophene), Poly[[2,2′-bithiophene]-5,5′-diyl(9,9-dioctyl-9H-fluorene-2,7-diyl)]

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About This Item

Formule linéaire :
(C37H44S2)n(C8H9)2
Numéro CAS:
Code UNSPSC :
12352103
Nomenclature NACRES :
NA.23

Pureté

99.9%

Forme

powder

Poids mol.

average Mn >20,000

Fluorescence

λex 400 nm; λem 497 nm in chloroform (at Mn = 20,000)

Propriétés du semi-conducteur

P-type (mobility=5×10−3 cm2/V·s)

Description générale

F8T2 is a fluorenated semiconducting polymer which can be used as a hole transporting layer with mobility of 0.02cm2V-1s-1. It is highly stable in vacuum and UV based environment. Its liquid crystallinity allows it to form a self-ordered nanostructure on organic thin films.
Typically soluble in THF, Dichloromethane, or Tolune. (c = 1%, typical appearance may be clear to turbid).
Polymer is end-capped with 3,5-dimethylbenzene.

Application

F8T2 can be majorly used in the fabrication of active layers for optoelectronics and energy based devices such as organic field effect transistors(OFETs), solar cells, light emitting diodes(LEDs) and electronic gas sensors.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Structural ordering in F8T2 polyfluorene thin film transistors.
Organic Field Effect Transistors II, 5217, 35-43 (2003)
Controlling of spectral and optical parameters of the F8T2 liquid-crystalline polymer (LCP) by molarity for optoelectronic devices.
Gunduz B.
Optik, 126(23), 4566-4573 (2015)
Modulating the charge injection in organic field-effect transistors: fluorinated oligophenyl self-assembled monolayers for high work function electrodes.
Fenwick O, et al.
Journal of Material Chemistry C, 3(13), 3007-3015 (2015)
Photovoltaic properties and charge dynamics in nanophase-separated F8T2/PCBM blend films.
Yasuda T, et al.
J. Photopolym. Sci. Technol., 25(3), 271-276 (2012)
Morana, M.; Bret, G.; Brabec, C.
Applied Physics Letters, 87, 153511-153511 (2005)

Articles

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

There is widespread demand for thin, lightweight, and flexible electronic devices such as displays, sensors, actuators, and radio-frequency identification tags (RFIDs). Flexibility is necessary for scalability, portability, and mechanical robustness.

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