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323446

Sigma-Aldrich

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonyme(s) :

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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About This Item

Formule linéaire :
(NH4)2MoS4
Numéro CAS:
15060-55-6
Poids moléculaire :
260.28
Numéro MDL:
MFCD00136013
Code UNSPSC :
12352302
ID de substance PubChem :
24859366
Nomenclature NACRES :
NA.23

Pureté

99.97% trace metals basis

Forme

crystalline

Pertinence de la réaction

reagent type: catalyst
core: molybdenum

Impuretés

≤350.0 ppm Trace Metal Analysis

Pf

>300 °C (lit.)

Chaîne SMILES 

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

Clé InChI

PQNOIAHNKHBLRN-UHFFFAOYSA-P

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Catégories apparentées

Application

Ring opening of aziridines leading to sulfides and disulfides.
This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.

Actions biochimiques/physiologiques

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)

Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Satoru Yamasaki et al.
The Journal of cell biology, 177(4), 637-645 (2007-05-16)
Zinc is an essential trace element required for enzymatic activity and for maintaining the conformation of many transcription factors; thus, zinc homeostasis is tightly regulated. Although zinc affects several signaling molecules and may act as a neurotransmitter, it remains unknown
George J Brewer
Current cancer drug targets, 5(3), 195-202 (2005-05-17)
Tetrathiomolybdate (TM) is a novel anticopper agent under development for use in Wilson's disease. It acts by forming a stable tripartite complex with serum albumin and copper, rendering the complexed copper unavailable for cellular uptake. TM is a very potent
Yu Cheng et al.
Molecular pharmaceutics, 16(8), 3489-3501 (2019-06-28)
Recently, multifunctional clearable inorganic theranostic nanoparticles have been attracting more and more attention. Protein-based nanoparticles can be cleared by the hepatobiliary system efficiently. In this work, ultrasmall gadolinium oxide (Gd2O3) nanoparticles, which possess the advantage of high longitudinal relaxation rate
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.
Lang, J-P. Tatsumi, K.
Inorganic Chemistry, 37, 6308-6308 (1998)
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