CRM43234

Methiocarb

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): Mercaptodimethur
• Empirical Formula (Hill Notation): C₁₁H₁₅NO₂S
• CAS Number: 2032-65-7
• Molecular Weight: 225.31
• Beilstein: 1881431
• MDL number: MFCD00055450
• UNSPSC Code: 41116107

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• storage temp.: 2-30°C
• SMILES string: CNC(=O)Oc1cc(C)c(SC)c(C)c1
• InChI: 1S/C11H15NO2S/c1-7-5-9(14-11(13)12-3)6-8(2)10(7)15-4/h5-6H,1-4H3,(H,12,13)
• InChI key: YFBPRJGDJKVWAH-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Methiocarb is a synthetic carbamate pesticide that shows broad biological activity. It is widely used for its insecticidal and molluscicidal activity against snails, rice insects, and also on fruit crops for its bird-repelling nature.
As per the commission implementing regulation (EU) 2019/1606 of 27th September 2019, methiocarb (expressed as a sum of methiocarb, methiocarb sulfone, and methiocarb sulfoxide) is not approved for use in the European Union. A maximum residue limit (MRLs) of 0.01 to 0.1 mg/kg has been set for the presence of methiocarb in various products of plant and animal origin as per Reg (EU) 2021/155. Methiocarb is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The methiocarb CRM may also find the following uses:

• Determination of methiocarb in water sample using boron-doped diamond electrode (BDDE) and differential pulse voltammetry
• Development of a method to simultaneously measure methiocarb and its metabolites in five food products of animal origin (milk, chicken, pork, beef, and eggs) by liquid chromatography-tandem mass spectrometry(LC-MS/MS)
• Extraction and quantification of six carbamate pesticide residues in water, fruit, and vegetable samples using dispersive liquid-liquid microextraction and high-performance liquid chromatography
• Simultaneous analysis of trace carbamate pesticide residues in tomato samples using graphene-based magnetic nanoparticles for their magnetic solid phase extraction and high-performance liquid chromatographic determination
• Pre-concentration of 13 pesticide residues using a silica-based MSU-1 mesoporous material and their subsequent determination by UPLC-MS/MS in environmental water samples
• Multi-residue determination of 200 pesticides and their metabolites in honeybee samples using liquid and gas chromatography coupled to tandem mass spectrometry

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H301 + H311 - H410
• Precautionary Statements: P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P361 + P364
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable