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56901

Sigma-Aldrich

Geranyl monophosphate lithium salt

≥95.0% (TLC)

Synonym(s):

(E)-3,7-Dimethyl-2,6-octadien-1-ol dihydrogen phosphate lithium salt, (E)-3,7-Dimethyl-2,6-octadien-1-yl phosphate lithium salt, Geranyl phosphate lithium salt

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About This Item

Empirical Formula (Hill Notation):
C10H19O4P · xLi+
CAS Number:
16750-99-5
Molecular Weight:
234.23 (free acid basis)
Beilstein:
1911590
UNSPSC Code:
12352106
NACRES:
NA.25

Quality Level

100

Assay

≥95.0% (TLC)

storage temp.

−20°C

InChI

1S/C10H19O3P/c1-9(2)5-4-6-10(3)7-8-13-14(11)12/h5,7,14H,4,6,8H2,1-3H3,(H,11,12)/p-1

InChI key

KMVHUYNPESFWSO-UHFFFAOYSA-M

Related Categories

Application

Geranyl monophosphate (GP) may be used to study the kinetics and substrate specificity of modified/mutated isopentenyl phosphate kinases. Such studies may lead to engineered IPK mutants capable of facilitating the chemoenzymatic synthesis of longer chain isoprenoid diphosphates from monophosphate precursors.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCBD0054V
BCBD9105V
BCBD9105
BCBD0054

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Geranylgeranyl pyrophosphate ammonium salt solution, ≥95% (TLC), ~1 mg/mL in methanol: NH4OH (7:3)

Sigma-Aldrich

G6025

Geranylgeranyl pyrophosphate ammonium salt

Mark F Mabanglo et al.
ACS chemical biology, 7(7), 1241-1246 (2012-04-27)
Isopentenyl phosphate kinase (IPK) catalyzes the ATP-dependent phosphorylation of isopentenyl phosphate (IP) to form isopentenyl diphosphate (IPP) during biosynthesis of isoprenoid metabolites in Archaea. The structure of IPK from the archeaon Thermoplasma acidophilum (THA) was recently reported and guided the
Mo Chen et al.
Biochemistry, 49(1), 207-217 (2009-11-26)
Archaea synthesize isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP), the essential building blocks of isoprenoid compounds, from mevalonate (MVA). However, an analysis of the genomes of several members of the Archaea failed to identify genes for the enzymes required to
Nikki Dellas et al.
ACS chemical biology, 5(6), 589-601 (2010-04-16)
The biosynthesis of isopentenyl diphosphate (IPP) from either the mevalonate (MVA) or the 1-deoxy-d-xylulose 5-phosphate (DXP) pathway provides the key metabolite for primary and secondary isoprenoid biosynthesis. Isoprenoid metabolism plays crucial roles in membrane stability, steroid biosynthesis, vitamin production, protein

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