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Halosulfuron-methyl

PESTANAL®, analytical standard

Synonym(s):

Methyl 3-chloro-5-(4,6-dimethoxy-2-pyrimidinylcarbamoylsulfamoyl)-1-methylpyrazole-4-carboxylate

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About This Item

Empirical Formula (Hill Notation):
C13H15ClN6O7S
CAS Number:
Molecular Weight:
434.81
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COC(=O)c1c(Cl)nn(C)c1S(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2

InChI

1S/C13H15ClN6O7S/c1-20-10(8(9(14)18-20)11(21)27-4)28(23,24)19-13(22)17-12-15-6(25-2)5-7(16-12)26-3/h5H,1-4H3,(H2,15,16,17,19,22)

InChI key

FMGZEUWROYGLAY-UHFFFAOYSA-N

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General description

Halosulfuron-methyl is a highly active postemergence sulfonylurea herbicide, which finds applications in weed control management.

Application

Halosulfuron-methyl may be used as a standard in the determination of halosulfuron methyl in water samples using liquid chromatography coupled with electrospray ionization mass spectrometry (LC/ES-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Confirmation and quantitation of selected sulfonylurea, imidazolinone, and sulfonamide herbicides in surface water using electrospray LC/MS.
Rodriguez M and Orescan B D.
Analytical Chemistry, 70(13), 2710-2717 (1998)
Transformation kinetics and mechanism of the sulfonylurea herbicides pyrazosulfuron ethyl and halosulfuron methyl in aqueous solutions.
Zheng W, et al.
Journal of Agricultural and Food Chemistry, 56(16), 7367-7372 (2008)
Determination and quantitation of sulfonylurea and urea herbicides in water samples using liquid chromatography with electrospray ionization mass spectrometric detection.
Ayano E, et al.
Analytica Chimica Acta, 507(2), 211-218 (2004)

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