I3502

α-Isonitrosopropiophenone

• Synonym(s): 1-Phenyl-1,2-propanedione-2-oxime, 2-(Hydroxyimino)propiophenone, NSC 5410
• Linear Formula: C₆H₅COC(=NOH)CH₃
• CAS Number: 119-51-7
• Molecular Weight: 163.17
• EC Number: 204-329-2
• MDL number: MFCD00002115
• UNSPSC Code: 12352100
• PubChem Substance ID: 57654301
• NACRES: NA.22

Properties

• mp: 113-115 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: C\C(=N/O)C(=O)c1ccccc1
• InChI: 1S/C9H9NO2/c1-7(10-12)9(11)8-5-3-2-4-6-8/h2-6,12H,1H3/b10-7+
• InChI key: YPINLRNGSGGJJT-JXMROGBWSA-N

Description

Application

Reactant involved in synthesis of:

• Cyclometalated iridium complexes for photophysical and electrochemical studies
• Hydroimidazothiazoles via iodination and cyclization reactions

Reactant involved in:

• Sonogashira coupling reactions
• Allylation of aromatic aldehydes using imidazole oside catalysts
• Beckmann rearrangement of α-oximinoketones

Reagent used in the colorimetric determination of urea

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves