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Key Documents

D206555

Sigma-Aldrich

Diphenyl phosphoryl chloride

99%

Synonym(s):

Diphenyl chlorophosphate, Diphenyl phosphorochloridate

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About This Item

Linear Formula:
(C6H5O)2POCl
CAS Number:
Molecular Weight:
268.63
Beilstein:
654130
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

10 mmHg ( 190 °C)

Quality Level

Assay

99%

form

liquid

refractive index

n20/D 1.55 (lit.)

bp

314-316 °C/272 mmHg (lit.)

density

1.296 g/mL at 25 °C (lit.)

SMILES string

ClP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H10ClO3P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H

InChI key

BHIIGRBMZRSDRI-UHFFFAOYSA-N

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Application

Phosphorylation reagent for protected serine and pyranoses.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

>235.4 °F - closed cup

Flash Point(C)

> 113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Tetrahedron Letters, 34, 2461-2461 (1993)
Carbohydrate Research, 223, 169-169 (1992)

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