C54007
Chloromethyl methyl sulfide
95%
Synonym(s):
Chlorodimethyl sulfide
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About This Item
Linear Formula:
CH3SCH2Cl
CAS Number:
Molecular Weight:
96.58
Beilstein:
1730851
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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Assay
95%
form
liquid
refractive index
n20/D 1.498 (lit.)
bp
105 °C (lit.)
density
1.153 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CSCCl
InChI
1S/C2H5ClS/c1-4-2-3/h2H2,1H3
InChI key
JWMLCCRPDOIBAV-UHFFFAOYSA-N
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Application
Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.
Caution
May darken in storage.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
62.6 °F - closed cup
Flash Point(C)
17 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis, 276-276 (1994)
Chemistry Letters (Jpn), 653-653 (1993)
Manuel Algarra et al.
The journal of physical chemistry. A, 124(10), 1911-1921 (2020-02-14)
UV photodecomposition of azidomethyl methyl sulfide (AMMS) yields a transient S-methylthiaziridine which rapidly evolves to S-methyl-N-sulfenylmethanimine at 10 K. This species was detected by infrared matrix isolation spectroscopy. The mechanism of the photoreaction of AMMS has been investigated by a
Organic Syntheses, 70, 177-177 (1992)
[Mutagenic activity of chlorodimethylsulfide and some of its aniline derivatives].
M Vito et al.
Bollettino della Societa italiana di biologia sperimentale, 61(6), 917-923 (1985-06-30)
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