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ALD00600

Sigma-Aldrich

Zhu-Yu Auxiliary

98%

Synonym(s):

1-Carboxy-1-methylethoxyammonium chloride, 2,2-Dimethyl aminooxyacetic, 2-(Aminooxy)-2-methylpropanoic acid hydrochloride

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About This Item

Empirical Formula (Hill Notation):
C4H10ClNO3
CAS Number:
89766-91-6
Molecular Weight:
155.58
MDL number:
MFCD08063911
UNSPSC Code:
12352101

Assay

98%

form

powder or crystals

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

availability

available only in USA

mp

150-165 °C

InChI

1S/C4H9NO3.ClH/c1-4(2,8-5)3(6)7;/h5H2,1-2H3,(H,6,7);1H

InChI key

ZJPZGAAOCIFBDI-UHFFFAOYSA-N

Application

The Zhu-Yu Auxiliary was reported by Jin-Quan Yu′s lab to be an effective auxiliary for the Pd(II)-catalyzed ß-C(sp3)-H(hetero)arylation of ketones.

Other Notes

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via ß-C(sp3)-H Activation

related product

Product No.
Description
Pricing

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H242

Hazard Classifications

Self-react. C

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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