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95372

Sigma-Aldrich

Bismuth

granular, ≥99.99% trace metals basis

Synonym(s):

Bi

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About This Item

Empirical Formula (Hill Notation):
Bi
CAS Number:
7440-69-9
Molecular Weight:
208.98
EC Number:
231-177-4
MDL number:
MFCD00134033
UNSPSC Code:
12161600
PubChem Substance ID:
57653676
NACRES:
NA.22

vapor pressure

<0.1 mmHg ( 20 °C)

Assay

≥99.99% trace metals basis

form

granular

reaction suitability

core: bismuth
reagent type: catalyst

resistivity

129 μΩ-cm, 20°C

bp

1560 °C (lit.)

mp

271 °C (lit.)
272 °C

density

9.8 g/mL at 25 °C (lit.)

SMILES string

[Bi]

InChI

1S/Bi

InChI key

JCXGWMGPZLAOME-UHFFFAOYSA-N

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General description

Bismuth is a silvery, very brittle metal with a high metallic luster. In the periodic table, it is next to lead. Bismuth has a variety of applications, including medicine, materials synthesis, organic synthesis, and catalysis . It is used in the production of malleable iron and as a catalyst in the manufacture of acrylic fibers . Additionally, bismuth promotes noble metal-based catalysts for the selective oxidation of alcohols, aldehydes and carbohydrates with molecular oxygen in liquid phases.

Application

Bismuth granules are used in the preparation of bismuth nanoparticles by solution dispersion method. It is a precursor to synthesize bismuth-silicate glasses.
Bismuth is used as a precursor in the synthesis of Cu3BiS3 based solar device.

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Modification of carbon screen-printed electrodes by adsorption of chemically synthesized Bi nanoparticles for the voltammetric stripping detection of Zn (II), Cd (II) and Pb (II).
Rico MAG, et al.
Talanta, 80(2), 631-635 (2009)
A simple way to prepare bismuth nanoparticles.
Zhao Y, et al.
Materials Letters, 58(5), 790-793 (2004)
The role of bismuth in the SOHIO process
Hanna TA
Coordination Chemistry Reviews, 248(5-6), 429-440 (2004)
Characterization of structural, thermal and mechanical properties of bismuth silicate glasses.
Bochentyn B, et al.
Journal of Non-Crystalline Solids, 439(2), 51-56 (2016)
B Arnaud et al.
Physical review letters, 110(1), 016405-016405 (2013-02-07)
By means of first principles calculations, we compute the effective electron-phonon coupling constant G(0) governing the electron cooling in photoexcited bismuth. G(0) strongly increases as a function of electron temperature, which can be traced back to the semimetallic nature of
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