665096
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
97%
Synonym(s):
Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
About This Item
Recommended Products
Assay
97%
form
powder
reaction suitability
core: rhenium
reagent type: catalyst
SMILES string
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI key
GIBDGLAUIKUJJX-UHFFFAOYSA-K
Application
- Enantioselective reduction of ketones and imines
- Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
- Synthesis of 2-deoxy-α glycosides
- Sulfurization of phosphorous(III) compounds with thiiranes
Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Certificates of Analysis (COA)
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Articles
Rhenium-Oxo Catalysts
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