316385
Potassium fluoride on alumina
extent of labeling: 40 wt. % loading
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About This Item
Linear Formula:
KF
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
form
solid
Quality Level
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
extent of labeling
40 wt. % loading
greener alternative category
SMILES string
[F-].[K+]
InChI
1S/FH.K/h1H;/q;+1/p-1
InChI key
NROKBHXJSPEDAR-UHFFFAOYSA-M
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Green etherification reagent of choice according to Glaxo-Smith-Kline's reagent guide.
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Potassium fluoride loaded alumina can be used to catalyze:
- Dehydration of alkyl and aryl aldoximes into nitriles may be catalyze by potassium fluoride loaded on alumina.
- Palladium-catalysed reactions to prepare allylic thiol derivatives.
- N-Alkylation of carboxamides.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Potassium fluoride doped on alumina: An efficient catalyst for conversion of aldoximes into nitriles.
Movassagh B and Shokri S
Synthetic Communications, 35(6), 887-890 (2005)
N-Alkylation of amides and N-heterocycles with potassium fluoride on alumina.
Yamawaki J, et al.
Chemistry Letters (Jpn), 10(8), 1143-1146 (1981)
Microwave mediated palladium-catalysed reactions on potassium fluoride/alumina without use of solvent.
Villemin D and Caillot F
Tetrahedron Letters, 42(4), 639-642 (2001)
Deniz Ekinci et al.
Bioorganic & medicinal chemistry, 19(2), 744-748 (2011-01-08)
Carbonic anhydrase (CA; EC 4.2.1.1) was purified from the gill of the teleost fish Dicentrarchus labrax (European seabass). The purification procedure consisted of a single step affinity chromatography on Sepharose 4B-tyrosine-sulfanilamide. The enzyme was purified 84.9-fold with a yield of
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