246794
Pentaerythritol tetraacrylate, Pentaerythritol triacrylate, and Trimethylolpropane triacrylate mixture
Synonym(s):
PTA/TMPTA mixture, Pentaerythritol acrylates mixture
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About This Item
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contains
300-400 ppm monomethyl ether hydroquinone as inhibitor
refractive index
n20/D 1.483
density
1.18 g/mL at 25 °C
SMILES string
O=C(C=C)OCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O.OCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O.CCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O
General description
Pentaerythritol tetraacrylate, Pentaerythritoltriacrylate, and Trimethylolpropane triacrylate mixture is a combination of three acrylate monomers widely used for cross-linking. The Pentaerythritol-based acrylate mixtureoffers advantages such as improved mechanical strength, flexibility, chemical resistance, and UV-curing properties. It finds applications in industries such as automotive coatings, electronics, packaging, and 3D bioprinting.
Application
Pentaerythritol tetraacrylate, Pentaerythritol triacrylate, and Trimethylolpropane triacrylate mixture can be used:
- As a cross-linking agent to synthesize biodegradable poly (1,3-trimethylene carbonate) (PTMC) networks with improved creep resistance and thermal stability. PMTC networks find application in the field of soft tissue engineering.
- As a monomer precursor to prepare light-curing dental composites via photopolymerization.
- To fabricate polymer-dispersed liquid crystal(PDLC) films with low driving voltage, moderately high contrast ratio, and fast response time. These PDLC films are utilized in optoelectronic devices such as OLEDs, FET, and solar cells.
- As a monomer mixture to prepare 3D bioprinting resins viaphotopolymerization.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1
Storage Class Code
10 - Combustible liquids
WGK
WGK 2
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Marc Hippler et al.
Nature communications, 10(1), 232-232 (2019-01-18)
Stimuli-responsive microstructures are critical to create adaptable systems in soft robotics and biosciences. For such applications, the materials must be compatible with aqueous environments and enable the manufacturing of three-dimensional structures. Poly(N-isopropylacrylamide) (pNIPAM) is a well-established polymer, exhibiting a substantial
Ming-Luan Chen et al.
Journal of chromatography. A, 1228, 183-192 (2011-08-06)
A novel poly(N-acryloyltris(hydroxymethyl)aminomethane-co-pentaerythritol triacrylate) (NAHAM-co-PETA) monolith was prepared in the 100 μm i.d. capillary and investigated for capillary liquid chromatography (cLC). The polymer monolith was synthesized by in situ polymerization of NAHAM and PETA in the presence of polyethylene glycol
Erhan Bat et al.
Biomacromolecules, 11(10), 2692-2699 (2010-09-16)
Biodegradable elastomeric poly(trimethylene carbonate) (PTMC) networks were efficiently formed by gamma irradiating the linear polymer in the presence of pentaerythritol triacrylate (PETA). The properties of networks formed upon irradiation of PTMC films containing (0, 1, 5 wt %) PETA as
Brent Vernon et al.
Journal of biomedical materials research. Part A, 64(3), 447-456 (2003-02-13)
A novel process for the preparation of water-borne biomaterials for hard tissue repair from injectable precursors is described, where the precursors form crosslinked materials in situ under physiological conditions. The precursors react by means of a Michael-type addition reaction that
Erhan Bat et al.
Macromolecular bioscience, 11(7), 952-961 (2011-04-12)
High-molecular-weight (co)polymers of trimethylene carbonate and D,L-lactide are efficiently crosslinked using PETA during gamma irradiation. Form-stable networks with gel contents of 86 ± 5 to 96 ± 1 are obtained from non-crystalline (co)polymers. Glass transition temperatures and elastic moduli of the networks can be
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