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Merck

443786

Sigma-Aldrich

Tetrachlorethen

ACS reagent, ≥99.0%

Synonym(e):

Ethylentetrachlorid, PCE

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About This Item

Lineare Formel:
CCl2=CCl2
CAS-Nummer:
Molekulargewicht:
165.83
Beilstein:
1361721
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352101
PubChem Substanz-ID:
NACRES:
NA.04

Qualität

ACS reagent

Qualitätsniveau

Dampfdichte

5.83 (vs air)

Dampfdruck

13 mmHg ( 20 °C)
19 mmHg ( 25 °C)

Assay

≥99.0%

Form

liquid

Methode(n)

FTIR: suitable

Verunreinigungen

≤0.05% water

Abdampfrückstand

≤0.0005%

Farbe

APHA: ≤10

Brechungsindex

n20/D 1.505 (lit.)

bp

121 °C (lit.)

mp (Schmelzpunkt)

−22 °C (lit.)

Löslichkeit

water: soluble 0.15 g/L at 25 °C

Dichte

1.623 g/mL at 25 °C (lit.)

SMILES String

Cl\C(Cl)=C(\Cl)Cl

InChI

1S/C2Cl4/c3-1(4)2(5)6

InChIKey

CYTYCFOTNPOANT-UHFFFAOYSA-N

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Allgemeine Beschreibung

Tetrachloroethylene (perchloroethylene, PCE), is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. It shows IR transparency as it has no C–H bonds making it an ideal solvent for IR spectroscopy. PCE is a man-made pollutant which is difficult to degrade. It is a ground water contaminant which has adverse effect on human health due to its potential toxicity and carcinogenicity. Some of the methods proposed for its degradation are Fenton oxidation treatment, reductive dehalogenation under methanogenic condition, and reduction using zero valent metal ions. One of the methods reported for its synthesis is by reacting ethylene dichloride and chlorine.

Anwendung

Tetrachloroethylene may be used as a film-forming electrolyte additive in the manufacture of lithium ion batteries. It may also be used as an extractant for the estimation of oil and grease in water by Fourier transform infrared spectroscopy (FT-IR).

Signalwort

Warning

Gefahreneinstufungen

Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Central nervous system

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

No data available

Flammpunkt (°C)

No data available


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Kunden haben sich ebenfalls angesehen

Validation of a FT-IR method for the determination of oils and grease in water using tetrachloroethylene as the extraction solvent.
Farmaki E, et al.
Desalination, 210(1), 52-60 (2007)
Tetrachloroethylene as new film-forming additive to propylene carbonate-based electrolytes for lithium ion batteries with graphitic anode.
Hu Y, et al.
Solid State Ionics, 176(1), 53-56 (2005)
Decomposition of aqueous tetrachloroethylene by Fenton oxidation treatment.
Yoshida M, et al.
Water Science and Technology, 42(1-2), 203-208 (2000)
Robert DM and Murphy B.
Chlorinated Solvents: A Forensic Evaluation, 84-85 (2013)
D Ryoo et al.
Nature biotechnology, 18(7), 775-778 (2000-07-11)
Tetrachloroethylene (PCE) is thought to have no natural source, so it is one of the most difficult contaminants to degrade biologically. This common groundwater pollutant was thought completely nonbiodegradable in the presence of oxygen. Here we report that the wastewater

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