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Merck

311413

Sigma-Aldrich

Perchlorsäure

ACS reagent, 60%

Synonym(e):

PCA

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About This Item

Lineare Formel:
HClO4
CAS-Nummer:
Molekulargewicht:
100.46
MDL-Nummer:
UNSPSC-Code:
12352106
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

ACS reagent

Qualitätsniveau

Dampfdruck

7 mmHg ( 25 °C)

Form

liquid

Eignung der Reaktion

reagent type: oxidant

Konzentration

60%

Verunreinigungen

≤0.001% N compounds
≤5 ppm Silicate and phosphate (as SIO2)

Glührückstand

≤0.003%

Farbe

APHA: ≤10

Dichte

1.535 g/mL at 25 °C

Anionenspuren

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.001%

Kationenspuren

Fe: ≤1 ppm
heavy metals: ≤1 ppm (by ICP)

SMILES String

OCl(=O)(=O)=O

InChI

1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)

InChIKey

VLTRZXGMWDSKGL-UHFFFAOYSA-N

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Anwendung

  • How microstructures, oxide layers, and charge transfer reactions influence double layer capacitances. Part 1: impedance spectroscopy and cyclic voltammetry to estimate electrochemically active surface areas (ECSAs).: Perchloric acid was employed for electrode cleaning and preparation, essential in electrochemical studies for accurate measurements and analysis in physical chemistry (Schalenbach et al., 2024).
  • Determination of phosphorus in commercially available milk using ion chromatography with perchloric acid deproteinization.: The research highlights the use of perchloric acid for deproteinization in ion chromatography, demonstrating its application in food chemistry and quality control (Yoshikawa et al., 2024).
  • Assessment of essential and potentially toxic metals in raw cow milk from Mukaturi town, Oromia Regional State, Ethiopia.: Perchloric acid was utilized for the digestion of milk samples, facilitating the determination of metal content through analytical techniques in environmental chemistry (Tola et al., 2024).
  • Fabrication and Characterization of an Electrochemical Platform for Formaldehyde Oxidation, Based on Glassy Carbon Modified with Multi-Walled Carbon Nanotubes and Electrochemically Generated Palladium Nanoparticles.: This study used perchloric acid in the modification of electrodes, crucial for developing advanced electrochemical sensors and analytical methods (Leniart et al., 2024).

Sonstige Hinweise

ACS Spezifikationen wie beim Produkt 244252, ausser der Konzentration

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 1 - Skin Corr. 1A - STOT RE 2

Zielorgane

Thyroid

Lagerklassenschlüssel

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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He-Ping Zhao et al.
Environmental science & technology, 47(3), 1565-1572 (2013-01-10)
We evaluated a strategy for achieving complete reduction of perchlorate (ClO(4)(-)) in the presence of much higher concentrations of sulfate (SO(4)(2-)) and nitrate (NO(3)(-)) in a hydrogen-based membrane biofilm reactor (MBfR). Full ClO(4)(-) reduction was achieved by using a two-stage
Martin G Liebensteiner et al.
Science (New York, N.Y.), 340(6128), 85-87 (2013-04-06)
Perchlorate and chlorate anions [(per)chlorate] exist in the environment from natural and anthropogenic sources, where they can serve as electron acceptors for bacteria. We performed growth experiments combined with genomic and proteomic analyses of the hyperthermophile Archaeoglobus fulgidus that show
Dipanwita Das et al.
Journal of the American Chemical Society, 135(10), 4018-4026 (2013-02-28)
Catalytic four-electron reduction of O2 by ferrocene (Fc) and 1,1'-dimethylferrocene (Me2Fc) occurs efficiently with a dinuclear copper(II) complex [Cu(II)2(XYLO)(OH)](2+) (1), where XYLO is a m-xylene-linked bis[(2-(2-pyridyl)ethyl)amine] dinucleating ligand with copper-bridging phenolate moiety], in the presence of perchloric acid (HClO4) in
Anna Weinberg et al.
Journal of abnormal psychology, 124(4), 878-889 (2015-07-28)
Depressive disorders are associated with significant economic and public health burdens as well as increased morbidity. Yet, perhaps due to the heterogeneous nature of the disease, prevention and intervention efforts are only moderately efficacious. A better understanding of core mechanisms
Dipanwita Das et al.
Journal of the American Chemical Society, 135(7), 2825-2834 (2013-02-12)
Selective two-electron plus two-proton (2e(-)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1'-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) (1; tepa = tris[2-(2-pyridyl)ethyl]amine) in acetone. The E(1/2)

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