208221

Chloriod

reagent grade, ≥95%

• Synonym(e): Iodmonochlorid
• Lineare Formel: ICl
• CAS-Nummer: 7790-99-0
• Molekulargewicht: 162.36
• EG-Nummer: 232-236-7
• MDL-Nummer: MFCD00011354
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329752040
• NACRES: NA.21

Eigenschaften

• Qualität: reagent grade
• Qualitätsniveau: 200
• Assay: ≥95%
• Form: solid or liquid
• bp: 97.4 °C (lit.)
• Dichte: 3.24 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: ClI
• InChI: 1S/ClI/c1-2
• InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Electrically conducting solution of ICl is obtained on dissolution of ICl in polar solvents. ICl is a green oxidizing agent and participates in the following transformations:

• aldose hemiacetals to the corresponding aldose lactones
• diarylmethanols to the corresponding diarylmethanones
• arylalkylmethanols to the corresponding arylalkylmethanones
• dialkylmethanols to the corresponding dialkylmethanones

Anwendung

Iodine monochloride (ICl) may be employed as a reagent in the following processes:

• Halogenation of methoxy and dimethoxybenzenes
• Synthesis of flavones.
• Preparation of 1-naphthaldehydes.

It may be used as an iodinating agent in the conversion of alkylboranes to alkyl iodides.

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H314,H335
• P-Sätze: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable