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M50834

Sigma-Aldrich

1-Methylimidazol

greener alternative

ReagentPlus®, 99%

Synonym(e):

N-Methylimidazole

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About This Item

Empirische Formel (Hill-System):
C4H6N2
CAS-Nummer:
616-47-7
Molekulargewicht:
82.10
Beilstein:
105197
EG-Nummer:
210-484-7
MDL-Nummer:
MFCD00005292
UNSPSC-Code:
12352005
PubChem Substanz-ID:
24896975
NACRES:
NA.22

Biologische Quelle

synthetic

Qualitätsniveau

200

Dampfdruck

0.4 mmHg ( 20 °C)

Produktlinie

ReagentPlus®

Assay

99%

Form

liquid

Selbstzündungstemp.

977 °F

Expl.-Gr.

15.7 %

Grünere Alternativprodukt-Eigenschaften

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Brechungsindex

n20/D 1.495 (lit.)

bp

198 °C (lit.)

mp (Schmelzpunkt)

−6 °C (lit.)

Löslichkeit

water: soluble

Dichte

1.03 g/mL at 25 °C (lit.)

Grünere Alternativprodukt-Kategorie

Aligned,

SMILES String

Cn1ccnc1

InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

InChIKey

MCTWTZJPVLRJOU-UHFFFAOYSA-N

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Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Anwendung

Co-catalyst for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

Rechtliche Hinweise

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Ähnliches Produkt

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Beschreibung
Preisangaben

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flammpunkt (°F)

197.6 °F - closed cup

Flammpunkt (°C)

92 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
0000255980
0000223672
STBK9121
0000188890
0000150113

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Pengfei Zhang et al.
Journal of chromatography. A, 1218(22), 3459-3465 (2011-04-19)
The development of mixed-mode stationary phase to achieve multiple separation capabilities in one column is very important for high performance liquid chromatography. In this paper, a new specific stationary phase based on grafting N-methylimidazolium to a monolithic silica column was
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also
Wen-Xin Chen et al.
The Journal of organic chemistry, 77(20), 9236-9239 (2012-10-02)
We report herein that amides are excellent N-sources in the NHC-Pd(II)-Im complex 1 catalyzed amination of aryl chlorides. In the presence of KO(t)Bu, various aryl chlorides and amides can react smoothly to give the corresponding aminated products in moderate to
Ganesh N Pandian et al.
Bioorganic & medicinal chemistry, 20(8), 2656-2660 (2012-03-13)
Epigenetic modifications that govern the gene expression are often overlooked with the design of artificial genetic switches. N-Methylpyrrole-N-methylimidazole (PI) hairpin polyamides are programmable small DNA binding molecules that have been studied in the context of gene regulation. Recently, we synthesized
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