E50000

Ethyltrifluoracetat

99%

• Synonym(e): Ethyl-trifluoracetat
• Lineare Formel: CF₃COOC₂H₅
• CAS-Nummer: 383-63-1
• Molekulargewicht: 142.08
• Beilstein: 1761411
• EG-Nummer: 206-851-6
• MDL-Nummer: MFCD00000419
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24894596
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.307 (lit.)
• bp: 60-62 °C (lit.)
• Dichte: 1.194 g/mL at 25 °C (lit.)
• SMILES String: CCOC(=O)C(F)(F)F
• InChI: 1S/C4H5F3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
• InChIKey: STSCVKRWJPWALQ-UHFFFAOYSA-N

Beschreibung

Anwendung

Ethyl trifluoroacetate can be used:

• To synthesize cyclopentenones or furans containing trifluoromethyl group from aromatic ynones.
• In the selective trifluoroacetylation of anilines catalyzed by 4-dimethylaminopyridine.
• As a starting material in the two-step electrosynthesis of trifluoroacetyltrimethylsilane (CF₃COSiMe₃).
• In the preparation of trifluoromethyl ketones via trifluoroacetic ester/ketone metathesis with alkyl aryl ketones.
• To synthesize o-fluorinated trifluoro acetophenones from substituted fluorobenzene.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H315,H318,H335
• P-Sätze: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 30.2 °F - closed cup
• Flammpunkt (°C): -1 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves