B56501

4-Bromanisol

≥99.0%

• Synonym(e): 1-Brom-4-methoxy-benzol
• Lineare Formel: BrC₆H₄OCH₃
• CAS-Nummer: 104-92-7
• Molekulargewicht: 187.03
• Beilstein: 1237590
• EG-Nummer: 203-252-1
• MDL-Nummer: MFCD00000097
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24891850
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥99.0%
• Form: liquid
• Brechungsindex: n20/D 1.564 (lit.)
• bp: 223 °C (lit.)
• mp (Schmelzpunkt): 9-10 °C (lit.)
• Dichte: 1.494 g/mL at 25 °C (lit.)
• SMILES String: COc1ccc(Br)cc1
• InChI: 1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
• InChIKey: QJPJQTDYNZXKQF-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Anwendung

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302,H315
• P-Sätze: P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313
• Gefahreneinstufungen: Acute Tox. 4 Oral - Skin Irrit. 2
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 2
• Flammpunkt (°F): 201.2 °F
• Flammpunkt (°C): 94 °C
• Persönliche Schutzausrüstung: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)