938726

ImPy-Dipop-Dipp

• Synonym(e): 5-(2,6-diisopropoxyphenyl)-2-(2,6-diisopropylphenyl)imidazo[1,5-a]pyridin-2-ium chloride
• Empirische Formel (Hill-System): C₃₁H₃₉ClN₂O₂
• CAS-Nummer: 2983007-49-2
• Molekulargewicht: 507.11
• UNSPSC-Code: 12352100

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Eignung der Reaktion: reaction type: Cross Couplings
• Farbe: white
• SMILES String: CC(C1=CC=CC(C(C)C)=C1[N+]2=CN3C(C4=C(OC(C)C)C=CC=C4OC(C)C)=CC=CC3=C2)C.[Cl-]
• InChI: 1S/C31H39N2O2.ClH/c1-20(2)25-13-10-14-26(21(3)4)31(25)32-18-24-12-9-15-27(33(24)19-32)30-28(34-22(5)6)16-11-17-29(30)35-23(7)8;/h9-23H,1-8H3;1H/q+1;/p-1
• InChIKey: XMDMIAJKGFBECK-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

ImPy-Dipop-Dipp is an NHC precursor developed in the Szostak group. The ligand is useful in a range of catalytic transformations, and is particulary well suited to the following: Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates, Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂), Buchwald-Hartwig amination of alkyl sulfoxides

Anwendung

Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂) or aryl sulfamates Buchwald-Hartwig amination of alkyl sulfoxides or aryl sulfamates

Leistungsmerkmale und Vorteile

ImPy-Dipop-Dipp is an asymmetric NHC ligand precursor. It forms air-and moisture stable complexes with transition metals and is particulary effective in palladium catalyzed cross-coupling reactions.