767654

cis-Dichlorobis(dimethyl sulfoxide)platinum(II)

97%

• Synonym(e): cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)₂Cl₂
• Empirische Formel (Hill-System): C₄H₁₂Cl₂O₂PtS₂
• CAS-Nummer: 22840-91-1
• Molekulargewicht: 422.25
• MDL-Nummer: MFCD00061452
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329767328
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: platinum; reagent type: catalyst
• mp (Schmelzpunkt): 218-224 °C
• SMILES String: Cl[Pt]Cl.CS(C)=O.CS(C)=O
• InChI: 1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
• InChIKey: KDADQDWVKZJTDQ-UHFFFAOYSA-L

Beschreibung

Allgemeine Beschreibung

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.

Anwendung

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:

• Catalyst in the oleum-mediated (SO₃-H₂SO₄) methane oxidation to form methyl bisulfate (MBS).
• Precursor in the synthesis of cyclometalated complexes.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable