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Merck

745618

Sigma-Aldrich

D205 Dye

95% (HPLC)

Synonym(e):

5-[[4-[4-(2,2-Diphenylethenyl)phenyl]-1,2,3,3a,4,8b-hexahydrocyclopent[b]indol-7-yl]methylene]-2-(3-octyl-4-oxo-2-thioxo-5-thiazolidinylidene)-4-oxo-3-thiazolidineacetic acid, Indoline dye D205, Purple dye

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About This Item

Empirische Formel (Hill-System):
C48H47N3O4S3
CAS-Nummer:
Molekulargewicht:
826.10
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Assay

95% (HPLC)

Form

powder

mp (Schmelzpunkt)

247-252 °C

λmax

531, 392 nm

SMILES String

S=C(N(CCCCCCCC)C/1=O)SC1=C(S/C2=C\C(C=C3)=CC4=C3N(C5=CC=C(C=C(C6=CC=CC=C6)C7=CC=CC=C7)C=C5)C8C4CCC8)/N(CC(O)=O)C2=O

InChI

1S/C48H47N3O4S3/c1-2-3-4-5-6-13-27-49-46(55)44(58-48(49)56)47-50(31-43(52)53)45(54)42(57-47)30-33-23-26-41-39(29-33)37-19-14-20-40(37)51(41)36-24-21-32(22-25-36)28-38(34-15-9-7-10-16-34)35-17-11-8-12-18-35/h7-12,15-18,21-26,28-30,37,40H,2-6,13-14,19-20,27,31H2,1H3,(H,52,53)/b42-30-,47-44+

InChIKey

WZGXSNHXTGGEGJ-PHBNZWDISA-N

Allgemeine Beschreibung

D205 Dye is an indoline dye widely used as an organic sensitizer that can be coated on metal oxide to improve its efficiency. It is majorly used in the development of high performing energy based devices.

Anwendung

D205 dye is a metal-free organic dye that can be used in dye sensitized solar cells (DSSCs). It can achieve a power conversion efficiency of 9.5%.
Photosensitive Red-Violet dye having excellent photoelectric conversion efficiency as a metal-free dye.

Efficiency of DSSC device - ? > 9.5%
Cell area: 0.25 cm2 (0.5 cm × 0.5 cm)
TiO2 Thickness: 5 μm
TiO2: screen printing
Electrolyte: 0.1 M LiI; 0.05 M I2; 0.6 M Dimethylpropylimidazolium
Iodide; 0.05 M t-Butylpyridine in 3-Methoxypropionitrile
Light source: AM1.5
Counter Electrode: Pt/Cr spatter glass
Dye adsorption: 30 °C/ in 3 hr. (t-BuOH/acetonitrile soln.)

Rechtliche Hinweise

Product of Mitsubishi Paper Mills; Ltd.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Journal of Materials Chemistry, 21(43), 17259-17264 (2011)
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Shibayama N, et al.
Chemical Communications (Cambridge, England), 51(64), 12795-12798 (2015)

Artikel

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm2.2

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