697257

Kupfer(I)-cyanid-di(lithiumchlorid)-Komplex

in anhydrous tetrahydrofuran

• Synonym(e): Copper(I) cyanide di(lithium chloride)
• Lineare Formel: CuCN · 2LiCl
• Molekulargewicht: 174.35
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329761902
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Eignung der Reaktion: core: copper; reagent type: catalyst
• Konzentration: in anhydrous tetrahydrofuran
• Dichte: 0.999 g/mL at 25 °C
• SMILES String: [Li]Cl.[Li]Cl.[Cu]C#N
• InChI: 1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
• InChIKey: QGXKBLXNBYNHBV-UHFFFAOYSA-L

Beschreibung

Anwendung

Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc and Grignard reagents. It is also a useful precursor to prepare organocuprate(I) reagents.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS08,GHS09
• Signalwort: Danger
• H-Sätze: H225,H300 + H310 + H330,H315,H319,H335,H336,H351,H410
• P-Sätze: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 2
• Flammpunkt (°F): 1.4 °F - closed cup - Solvent
• Flammpunkt (°C): -17 °C - closed cup - Solvent
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter