695459

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-Phosphaadamantan

97%

• Synonym(e): 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.1^3,7]decan, ^meCgPPh
• Empirische Formel (Hill-System): C₁₆H₂₁O₃P
• CAS-Nummer: 97739-46-3
• Molekulargewicht: 292.31
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761744
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• mp (Schmelzpunkt): 106-111 °C
• Funktionelle Gruppe: phosphine
• SMILES String: CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2
• InChI: 1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
• InChIKey: AVVSJWUWBATQBX-UHFFFAOYSA-N

Beschreibung

Anwendung

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:

• As a ligand to synthesize complexes for hydroformylation catalysis.
• To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable