689785

(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-Diylhydrogenphosphat

≥97.0% (qNMR)

• Synonym(e): (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis-[2,4,6-tris-(1-methylethyl)-phenyl]-dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-oxid, (S)-3,3′-Bis-(2,4,6-triisopropyl-phenyl)-1,1′-bi-2-naphthol-cyclophosphat
• Empirische Formel (Hill-System): C₅₀H₅₇O₄P
• CAS-Nummer: 874948-63-7
• Molekulargewicht: 752.96
• MDL-Nummer: MFCD10567009
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761289
• NACRES: NA.22

Eigenschaften

• Assay: ≥97.0% (qNMR)
• Form: lumps
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Grünere Alternativprodukt-Kategorie: , Aligned
• SMILES String: CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c-4c2OP(O)(=O)Oc5c(cc6ccccc6c-45)-c7c(cc(cc7C(C)C)C(C)C)C(C)C
• InChI: 1S/C50H57O4P/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32H,1-12H3,(H,51,52)
• InChIKey: AGQAQYPGJDBIQR-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)