469785

Benzylglycidylether

99%

• Synonym(e): (Benzyloxymethyl)oxirane, (±)-O-Benzylglycidol, 1-(Benzyloxy)-2,3-epoxypropane, 2-[(Phenylmethoxy)methyl]oxirane, 2-[[(Benzyloxy)methyl]oxy]oxirane, 3-(Benzyloxy)-1,2-epoxypropane, Glycidyl benzyl ether, [(Phenylmethoxy)methyl]oxirane
• Empirische Formel (Hill-System): C₁₀H₁₂O₂
• CAS-Nummer: 2930-05-4
• Molekulargewicht: 164.20
• EG-Nummer: 220-899-5
• MDL-Nummer: MFCD00068664
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24870484
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 99%
• Brechungsindex: n20/D 1.5170 (lit.)
• bp: 70-73 °C/11 mmHg (lit.)
• Dichte: 1.077 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ether; phenyl
• Lagertemp.: 2-8°C
• SMILES String: C(OCc1ccccc1)C2CO2
• InChI: 1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2
• InChIKey: QNYBOILAKBSWFG-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Benzyl glycidyl ether is a glycidyl derivative. Rac-/(R)-benzyl glycidyl ether participates in the synthesis of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s. Biocatalytic resolution of racemic benzyl glycidyl ether by Talaromyces flavus has been described. Resolution of benzyl glycidyl ether to (S)-benzyl glycidyl ether with 30% ee and (R)-3-benzyloxypropane-1,2-diol with 40% ee by whole Bacillus alcalophilus cells has been reported. It reacts with K^-, K⁺(15-crown-5)₂ to afford potassium glycidoxide and bibenzyl.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter