452823

(+)-Bis[(R)-1-phenylethyl]amin -hydrochlorid

99%

• Synonym(e): (+)-Bis[(R)-α-methylbenzyl]amin -hydrochlorid, [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amin
• Lineare Formel: [C₆H₅CH(CH₃)]₂NH
• CAS-Nummer: 23294-41-9
• Molekulargewicht: 225.33
• Beilstein: 3590931
• MDL-Nummer: MFCD00243088
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 24868728
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 99%
• Optische Aktivität: [α]20/D +199.0°, neat
• Optische Reinheit: ee: ≥99% (GLC)
• Brechungsindex: n20/D 1.5523 (lit.)
• bp: 86 °C/0.05 mmHg (lit.)
• Dichte: 0.985 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine; phenyl
• SMILES String: C[C@@H](N[C@H](C)c1ccccc1)c2ccccc2
• InChI: 1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1
• InChIKey: NXLACVVNHYIYJN-ZIAGYGMSSA-N

Beschreibung

Anwendung

(+)-Bis[(R)-1-phenylethyl]amine can be used:

• In the synthesis of β-amino acids.
• In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
• To induce enantioselectivity in the deprotonation of prochiral ketones.
• As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
• In the synthesis of chiral phosphoramidite ligands.
• To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): >235.4 °F - closed cup
• Flammpunkt (°C): > 113 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter