423602

Ethyl-cis-3-iodacrylat

98%

• Lineare Formel: ICH=CHCO₂C₂H₅
• CAS-Nummer: 31930-36-6
• Molekulargewicht: 226.01
• MDL-Nummer: MFCD00209584
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24866512
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.533 (lit.)
• bp: 85 °C/20 mmHg (lit.)
• Dichte: 1.765 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ester; iodo
• Lagertemp.: 2-8°C
• SMILES String: [H]\C(I)=C(/[H])C(=O)OCC
• InChI: 1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-
• InChIKey: AELYFQSZXFFNGP-ARJAWSKDSA-N

Beschreibung

Allgemeine Beschreibung

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.

Anwendung

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

• vinyl sulfides
• (Z)-1-iodohept-1-en-3-ol
• (E)-1-iodohept-1-en-3-ol
• (Z)-β-iodoacrolein
• 6-oxo-M₁Guo

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 210.2 °F - closed cup
• Flammpunkt (°C): 99 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter