420697

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamin

96%

• Synonym(e): N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine
• Lineare Formel: C₆H₅CH₂N(CH₂OCH₃)CH₂Si(CH₃)₃
• CAS-Nummer: 93102-05-7
• Molekulargewicht: 237.41
• MDL-Nummer: MFCD00674005
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 24866346
• NACRES: NA.22

Eigenschaften

• Assay: 96%
• Form: liquid
• Brechungsindex: n20/D 1.492 (lit.)
• bp: 76 °C/0.3 mmHg (lit.)
• Dichte: 0.928 g/mL at 25 °C (lit.)
• SMILES String: COCN(Cc1ccccc1)C[Si](C)(C)C
• InChI: 1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
• InChIKey: RPZAAFUKDPKTKP-UHFFFAOYSA-N

Beschreibung

Anwendung

Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.

Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 150.8 °F - closed cup
• Flammpunkt (°C): 66 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter