341347

Bis(diisopropylamin)chlorphosphin

≥95.0%

• Synonym(e): Chlorobis(N,N-diisopropyl)phosphoramidite, Chlorobis(N,N-diisopropylamino)phosphine, Tetraisopropylphosphorodiamidous chloride
• Lineare Formel: [[(CH₃)₂CH]₂N]₂PCl
• CAS-Nummer: 56183-63-2
• Molekulargewicht: 266.79
• MDL-Nummer: MFCD00061482
• UNSPSC-Code: 12352001
• PubChem Substanz-ID: 24860930
• NACRES: NA.22

Eigenschaften

• Assay: ≥95.0%
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• mp (Schmelzpunkt): 100-104 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
• InChI: 1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
• InChIKey: FEHUTHGOLLQBNW-UHFFFAOYSA-N

Beschreibung

Anwendung

Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.

It is also can be used to synthesize:

• acyclic N-phosphonio imine catalyst for selective epoxidations
• boryl-substituted methylenephosphonium derivatives

Sonstige Hinweise

Contains varying amounts of diisopropylamine hydrochloride

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges