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Sigma-Aldrich

Zinkphthalocyanin

Dye content 97 %

Synonym(e):

Phthalocyanin Zinksalz

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About This Item

Empirische Formel (Hill-System):
C32H16N8Zn
CAS-Nummer:
14320-04-8
Molekulargewicht:
577.91
Beilstein:
4121852
EG-Nummer:
238-262-5
MDL-Nummer:
MFCD00041955
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24860701
NACRES:
NA.23

Zusammensetzung

Dye content, 97%

Eignung der Reaktion

reagent type: catalyst
core: zinc

λmax

701 nm

Energie der Orbitale

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

Leistung von OPV-Bauelementen

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

SMILES String

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChIKey

PODBBOVVOGJETB-UHFFFAOYSA-N

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Allgemeine Beschreibung

Zinc (II) phthalocyanine (ZnPc) complexes show photosensitizing properties. Phthalocyanines show significant Π−Π interactions and easy formation of H aggregates.

Anwendung

Zinc phthalocyanine finds general applications in industry (catalysts, photoconductors etc) and biomedical (photodynamic therapy, PDT). ZnPc may be used to photooxidise cyclohexane. A study reports functionalization of polymer membrane with ZnPc.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Ye-Liang Wang et al.
Chimia, 66(1-2), 31-37 (2012-05-02)
We report on high-resolution STM measurements with modified probe tips. First, both the rest atoms and adatoms of a Si(111)-7×7 surface are observed simultaneously. The visibility of rest atoms is dependent upon the sample bias voltage (less than -0.7 V)
Anamika Ray et al.
The journal of physical chemistry. B, 116(39), 11979-11998 (2012-08-23)
The present article reports photophysical studies on supramolecular interaction of a zinc phthalocyanine derivative, namely, zinc-2,9,16,23-tetra-tert-butyl phthalocyanine (1) with C(60) and C(70) in solvents having varying polarity, i.e., toluene and 1,2-dichlorobenzene (DCB). The interesting feature of the present work is
Effect of blend layer morphology on performance of ZnPc:C60-based photovoltaic cells
Zeng, W.; et al.
Applied Physics Letters, 97, 133304-133304 (2010)
Thandekile P Mthethwa et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 4922-4930 (2013-02-07)
A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed
Sean Marrache et al.
Integrative biology : quantitative biosciences from nano to macro, 5(1), 215-223 (2012-07-27)
A therapeutic technology that combines the phototoxic and immune-stimulating ability of photodynamic therapy (PDT) with the widespread effectiveness of the immune system can be very promising to treat metastatic breast cancer. We speculated that the knowledge of molecular mechanisms of
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