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Sigma-Aldrich

Perfluor(methylcyclohexan)

technical grade, 90%

Synonym(e):

(Trifluormethyl)-undecafluor-cyclohexan, Perfluormethylcyclohexan

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About This Item

Lineare Formel:
C6F11CF3
CAS-Nummer:
355-02-2
Molekulargewicht:
350.05
Beilstein:
1915981
EG-Nummer:
206-573-5
MDL-Nummer:
MFCD00001468
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24858283
NACRES:
NA.22

Qualität

technical grade

Qualitätsniveau

100

Assay

90%

Form

liquid

Brechungsindex

n17/D 1.285 (lit.)

bp

76 °C (lit.)

Dichte

1.787 g/mL at 25 °C (lit.)

SMILES String

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

InChIKey

QIROQPWSJUXOJC-UHFFFAOYSA-N

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Allgemeine Beschreibung

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Anwendung

Perfluoro(methylcyclohexane) can be used as:
  • A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
  • A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves

Analysenzertifikate (COA)

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Sigma-Aldrich

469629

Poly[4,5-difluor-2,2-bis(trifluormethyl)-1,3-dioxol-co-tetrafluorethylen]

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To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
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We have developed a new emulsion template method for the synthesis of poly(methylmethacrylate) (PMMA) hollow nanoparticles with different sizes. This synthetic method involves sequential ultrasonic irradiation (20 kHz → 500 kHz → 1.6 MHz → 2.4 MHz → 5.0 MHz) for acoustic emulsification of a water-insoluble fluorous solvent such as perfluoromethylcyclohexane (PFMCH) in
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Biology of the neonate, 87(1), 60-65 (2004-10-07)
To test the hypothesis that intrapulmonary perfluorochemical (PFC) liquid may induce hypothermia, and to compare the effects of internal (IC), external (EC), and combined cooling techniques (EC + IC), 14 juvenile rabbits were randomized to EC by a cold blanket
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