282146

(1R)-(−)-Campher-10-sulfonsäure

98%

• Synonym(e): (−)-Campher-10-sulfonsäure, (1R)-(−)-10-Camphersulfonsäure, (1R)-Campher-10-sulfonsäure
• Empirische Formel (Hill-System): C₁₀H₁₆O₄S
• CAS-Nummer: 35963-20-3
• Molekulargewicht: 232.30
• Beilstein: 2809676
• EG-Nummer: 252-817-9
• MDL-Nummer: MFCD00064158
• UNSPSC-Code: 12352106
• PubChem Substanz-ID: 24857020
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Optische Aktivität: [α]20/D −21°, c = 2 in H₂O
• mp (Schmelzpunkt): 198 °C (dec.) (lit.)
• SMILES String: [H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
• InChI: 1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
• InChIKey: MIOPJNTWMNEORI-XVKPBYJWSA-N

Beschreibung

Allgemeine Beschreibung

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Anwendung

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges